The instructions below reference the VTC WiFi network, but the instructions are the same for each institution (CCV, NVU, Castleton, and VTC). Android devices vary greatly, so these directions may not exactly match your device but the general gist is the same.
Start by opening your WiFi settings, either from the Settings app or via the Quick Access Bar, accessed by swiping down from the top of the screen. Chromebooks will need to click the WiFi icon in the lower right corner of the screen. Then click on the campus network you’d like to connect to:

You will then be prompted to enter some additional information. Set the options as listed below:
EAP Method = PEAP
Phase 2 Authentication = MSCHAPv2
CA Certificate = Unspecified or Do Not Validate

Scroll down to fill out the rest of the form as such:
Identity = Your VSC Username
Anonymous Identity = (leave this blank)
Password = Your VSC Password
Domain = vsc.edu
After filling out the form click Connect. Your device will now connect to the campus WiFi when in range